For an exothermic reaction the change in enthalpy is ________.

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  1. positive
  2. neutral
  3. negative
  4. constant

Answer (Detailed Solution Below)

Option 3 : negative
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Explanation:

Exothermic reaction: it is the reaction in which heat goes out from the system or heat is dissipated from the system. 

  • The change in enthalpy is negative in exothermic reaction ΔH < 0.
  • It is because the energy released by the reaction is more than the energy used by the reaction.
  • In thermodynamics generally when heat flows out of the system, the sign convention we use is negative.

Change in enthalpy:

  • In chemical reactions enthalpy changes is equal to the difference between energy used to break bonds and energy gained by the formation of new bonds.
  • It describes the energy change at constant pressure.
  • at constant pressure from first law of thermodynamics (δQ)p = dh
  • sign convention for heat dissipation from the system δQ < 0 ⇒ dh < 0
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