Question
Download Solution PDFFor an exothermic reaction the change in enthalpy is ________.
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFExplanation:
Exothermic reaction: it is the reaction in which heat goes out from the system or heat is dissipated from the system.
- The change in enthalpy is negative in exothermic reaction ΔH < 0.
- It is because the energy released by the reaction is more than the energy used by the reaction.
- In thermodynamics generally when heat flows out of the system, the sign convention we use is negative.
Change in enthalpy:
- In chemical reactions enthalpy changes is equal to the difference between energy used to break bonds and energy gained by the formation of new bonds.
- It describes the energy change at constant pressure.
- at constant pressure from first law of thermodynamics (δQ)p = dh
- sign convention for heat dissipation from the system δQ < 0 ⇒ dh < 0
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