Allene must have which of the following type of hybridised carbon? 

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. sp3
  2. sp2
  3. sp
  4. sp3d

Answer (Detailed Solution Below)

Option 3 : sp
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CONCEPT:

Hybridization in Allene

  • Allene (C3H4) is a molecule where two double bonds are connected to the central carbon atom.
  • The structure of allene consists of:
    • A central carbon atom bonded to two terminal carbon atoms via double bonds.
    • The central carbon forms two sigma bonds and two pi bonds.
  • For carbon atoms in double bonds:
    • The central carbon atom in allene is sp hybridized because it forms two sigma bonds and has two perpendicular pi bonds.
    • The terminal carbon atoms are sp2 hybridized because they form one sigma bond with the central carbon and one pi bond.

EXPLANATION:

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  • In allene:
    • The central carbon atom has two linear bonds (C=C bonds) and is sp hybridized.
    • This hybridization allows the central carbon to form two perpendicular π systems, giving the molecule its unique geometry.

Therefore, the correct answer is Option 3: The central carbon in allene is sp hybridized.

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