Which of the following reagents is used to reduce benzaldehyde to benzyl alcohol?

  1. NaBH4
  2. Zn dust
  3. Zn/Hg with HCl
  4. Cu/H2SO4

Answer (Detailed Solution Below)

Option 1 : NaBH4

Detailed Solution

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CONCEPT:

Reduction of Aldehydes to Alcohols

  • Aldehydes, like benzaldehyde, can be reduced to primary alcohols (such as benzyl alcohol) using specific reducing agents.
  • The choice of reducing agent depends on the reactivity and the type of reduction required.

EXPLANATION:

  • NaBH4 (Sodium borohydride) — NaBH4 is a mild reducing agent commonly used to reduce aldehydes and ketones to their corresponding alcohols. It selectively reduces benzaldehyde to benzyl alcohol. 
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  • Zinc dust acts as a reducing agent. Phenol undergoes reduction reaction in presence of zinc dust. Reduction reaction means the addition of electrons or removal of oxygen or addition of hydrogen.
  • Zn/Hg with HCl (Clemmensen reduction) — This reagent is used for the reduction of ketones and aldehydes to alkanes, not alcohols.
  • Cu/H2SO4 — This reagent is not commonly used for the reduction of aldehydes to alcohols and is more involved in oxidation or other types of reactions.

CONCLUSION:

  • NaBH4 is the reagent used to reduce benzaldehyde to benzyl alcohol.
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