The term ‘Catenation’ is used to define a unique property of carbon. Which of the following gives the correct definition of catenation?  

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  1. Unique ability to form bonds with other atoms of carbon. 
  2. Unique ability to form bonds with other atoms of hydrogen. 
  3. Unique ability to form bonds with other atoms of nitrogen. 
  4. Unique ability to form bonds with other atoms of oxygen.  

Answer (Detailed Solution Below)

Option 1 : Unique ability to form bonds with other atoms of carbon. 
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Detailed Solution

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The Correct answer is Unique ability to form bonds with other atoms of carbon.

Key Points

  • Catenation is the property by which carbon atoms form strong covalent bonds with other carbon atoms to produce long chains, branched structures, or rings.
  • This unique property arises due to the small size of carbon and the strength of the carbon-carbon bond, which is stronger than bonds formed by most other elements with themselves.
  • Carbon exhibits this property more prominently than other elements because of its ability to form single, double, and triple covalent bonds with itself.
  • Catenation allows carbon to form a vast number of compounds, making it the basis of organic chemistry and life.
  • Examples of compounds formed due to catenation include hydrocarbons (alkanes, alkenes, alkynes), as well as more complex molecules like proteins, carbohydrates, and DNA.
  • This property also explains the diversity of carbon compounds, which is unmatched by any other element in the periodic table.

 Additional Information

  • Unique ability to form bonds with other atoms of hydrogen
    • Hydrogen bonds with carbon to form hydrocarbons, but this does not define the property of catenation.
    • Hydrocarbons like methane (CH₄) are formed due to the bonding between carbon and hydrogen, but this is not specific to the unique bonding of carbon with itself.
  • Unique ability to form bonds with other atoms of nitrogen
    • Nitrogen can form bonds with carbon in amino acids and other organic molecules, but it does not exhibit the extensive catenation property like carbon.
    • Nitrogen primarily forms triple bonds in diatomic nitrogen (N₂), which is stable but unrelated to carbon's catenation.
  • Unique ability to form bonds with other atoms of oxygen
    • Oxygen forms bonds with carbon in functional groups like alcohols (-OH), carboxylic acids (-COOH), and ketones (>C=O).
    • However, oxygen does not form long chains or networks by bonding with itself, unlike carbon.
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