The representation of rate of reaction in terms of concentration of the reactants is known as

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  1. Order of reaction
  2. Rate expression
  3. Randomness
  4. Stoichiometric coefficient

Answer (Detailed Solution Below)

Option 2 : Rate expression
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The correct answer is Rate expression.

Key Points

  • The rate expression is a mathematical representation that relates the rate of reaction to the concentration of reactants.
  • It is often written in the form: rate = k[A]^m[B]^n, where k is the rate constant, and m and n are the orders of the reaction with respect to reactants A and B, respectively.
  • The exponents m and n in the rate expression indicate how the rate of reaction depends on the concentration of each reactant.
  • Determining the rate expression is crucial for understanding the kinetics of a chemical reaction and predicting how changes in concentration affect the reaction rate.

Additional Information

  • Order of Reaction:
    • The order of reaction with respect to a reactant is the power to which its concentration term in the rate equation is raised.
    • The overall order of reaction is the sum of the orders with respect to each reactant present in the rate expression.
  • Rate Constant (k):
    • The rate constant is a proportionality constant in the rate expression that is specific to a particular reaction at a given temperature.
    • Its units vary depending on the overall order of the reaction.
  • Stoichiometric Coefficient:
    • Stoichiometric coefficients are the numbers that appear before the reactants and products in a balanced chemical equation.
    • They indicate the relative amounts of each substance involved in the reaction.
  • Randomness:
    • In the context of chemical reactions, randomness often refers to the entropy change associated with the reaction.
    • Entropy is a measure of the disorder or randomness in a system.
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