A potential difference develops between the electrode and the electrolyte which is called

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  1. Electrode potential 
  2. Cell potential
  3. Cell electromotive force
  4. Standard electrode potential

Answer (Detailed Solution Below)

Option 1 : Electrode potential 
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The correct answer is Electrode Potential.

Key Points

  • Electrode potential is the potential difference developed between an electrode and its surrounding electrolyte due to the tendency of the electrode to gain or lose electrons.
  • The electrode potential is measured relative to a reference electrode, commonly the Standard Hydrogen Electrode (SHE).
  • Electrode potential is a fundamental concept in electrochemistry and is used to determine the feasibility and direction of redox reactions.
  • It can be expressed as standard electrode potential when measured under standard conditions (298 K temperature, 1 M concentration, and 1 atm pressure).
  • The sign of the electrode potential indicates whether the electrode acts as an anode (oxidation occurs) or a cathode (reduction occurs).

Additional Information

  • Cell Potential: The overall voltage of an electrochemical cell, calculated as the difference between the cathode and anode electrode potentials.
  • Electromotive Force (EMF): The maximum potential difference between two electrodes of a cell when no current flows through the cell.
  • Standard Electrode Potential (E°): The electrode potential measured under standard conditions, used as a reference to predict reaction spontaneity.
  • Redox Reaction: A chemical process involving the transfer of electrons between two species, forming the basis for electrochemical cell reactions.
  • Reference Electrode: An electrode with a stable and well-defined potential, such as the Standard Hydrogen Electrode (SHE), used for comparison in electrochemical measurements.
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